- 고온석탄가스에서 황화물을 제거하기 위한 다공성 흡착제의 개발 -II. 산화아연의 황화반응에 관한 연구-
- ㆍ 저자명
- 서인식,이재복,류경옥
- ㆍ 간행물명
- 한국환경위생학회지
- ㆍ 권/호정보
- 1988년|14권 1호|pp.11-22 (12 pages)
- ㆍ 발행정보
- 한국환경보건학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Calcium oxide, lithium oxide and titanium oxide were investigated as additives of zinc oxide for the removal of hydrogen sulfide at high temperature. This experiment was performed in the range of 1.0-2.0 vol.% H$_2$S concentration at 623-873 K reaction temperature, using a thermogravimetric analyzer. A pore blocking model was found to fit the reaction rate and the kinetics data were sucessfully expressed by this model. The reactions between additive sorbents and hydrogen sulfide were first order with respect to hydrogen sulfide concentration in a gaseous mixture with nitrogen. Among the used sorbents, ZnO-CaO 0.5 at.% and ZnO-TiO$_2$ 2.0 at.% sorbents had the best additive effects on the sulfidation reaction between additive sorbents and hydrogen sulfide, whereas the ZnO-Li$_2$O sorbents were ineffective.