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자외선조사에 의한 나일론6 필름에의 아크릴산 그라프트중합
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  • 자외선조사에 의한 나일론6 필름에의 아크릴산 그라프트중합
  • Ultraviolet Irradiation Graft Polymerization of Acrylie Acid onto Nylon 6 Film
저자명
신성철,김상율,송석규,Sin. Seong-Cheol,Kim. Sang-Yul,Song. Seok-Gyu
간행물명
韓國纖維工學會誌
권/호정보
1989년|26권 3호|pp.43-50 (8 pages)
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한국섬유공학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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The grafting of acrylic acid (AA) onto biaxially oriented nylon 6 film has been investigated by simultaneous irradiation technique in the aqueous solution in the presence of benzophenone (BP) as a photosensitizer. The effects of various reaction conditions involving monomer concentration, photosensitizer concentration, reaction time and temperature were studied. The grafting yield was increased with increasing AA and BP concentration up to limiting value and then decreased. The grafting yield increased with reaction time up to 90 min. and then levelled off. The grafting rate was increased with increasing the reaction temperature up to 6$0^{circ}C$ but above that temperature decreased. The crystallinity of grafted film, evaluated from the result of DSC, was generally decreased with increasing grafting yield. The mechanical properties of grafted samples were also examined by the tensile tester. It has been found that the contact angle was decreased and the moisture regain and the degree of swelling were increased with increasing the grafting yield.