기관회원 [로그인]
소속기관에서 받은 아이디, 비밀번호를 입력해 주세요.
개인회원 [로그인]

비회원 구매시 입력하신 핸드폰번호를 입력해 주세요.
본인 인증 후 구매내역을 확인하실 수 있습니다.

회원가입
서지반출
폴리부틸레 테레프탈레이트 합성에 관한 연구
[STEP1]서지반출 형식 선택
파일형식
@
서지도구
SNS
기타
[STEP2]서지반출 정보 선택
  • 제목
  • URL
돌아가기
확인
취소
  • 폴리부틸레 테레프탈레이트 합성에 관한 연구
  • A Study on Preparation of Polybutylene Terephthalate
저자명
조순채,최재호
간행물명
韓國纖維工學會誌
권/호정보
1989년|26권 7호|pp.62-75 (14 pages)
발행정보
한국섬유공학회
파일정보
정기간행물|
PDF텍스트
주제분야
기타
이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

In the process that uses terephthalic acid(TPA) and 1,4-butandio(BD) for the production of polybutylene terephthalate(PBT), the influences of reaction conditions on % reaction, Xn(the degree of polymerization of oligo-PBT), and %BDlongrightarrowTHF(tetrahydrofuran) were investigated. With increasing mole ratio of BD:TPA, %BDlongrightarrowTHF increased and Xn decreased, but with increasing tetrabutyltitanate(TBT) concentration, %BDlongrightarrowTHF decreased and Xn increased. %BDlongrightarrowTHF increased greatly with increasing the reaction temperature in the rang of temperature between 21$0^{circ}C$ and 23$0^{circ}C$ and the increase of temperature afforded great effect to Xn in the range of temperature up to 21$0^{circ}C$. Drop-wise feed of BD was an effective method for the minimization of THF formation. Assuming that the reactions occurring in both the formation of oligo-PBT from BD/TPA and of THF from BD would be of the first order with respect to H2O and THF respectively, the kinetic reaction constants -KH2O and KTHF-were determined from the results which had been examined in the temperature range between 19$0^{circ}C$ and 21$0^{circ}C$. KH2O /KTHF values were plotted versus the reaction temperature, and the temparature-raising-condition on reaction time for minimal loss of BD by hydration to THF was described.