- Citrate, Nitrate Process에 의한 YBa2Cu3O7-x초전도 분말합성
- ㆍ 저자명
- 박수련,김윤호
- ㆍ 간행물명
- 요업학회지
- ㆍ 권/호정보
- 1989년|26권 2호|pp.221-227 (7 pages)
- ㆍ 발행정보
- 한국세라믹학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
To investigate the development and densification YBa2Cu3O7-x(1-2-3) superconducting phase, the 1-2-3 phase powders have been prepared by citrate and nitrate processes with changing calcination temperature. Nearly pure 1-2-3 phase peaks have been obtained by calcining the precursor in air at 90$0^{circ}C$ for 2.5h in citrate process but at 95$0^{circ}C$ for 2.5h in nitrate process. The sintering density of citrate derived sample calcined at 80$0^{circ}C$ has been about 4% higher than that calcined at 90$0^{circ}C$, although the compacting density has been lower at 80$0^{circ}C$ calcination. This can be explained that the 1-2-3 phase particles formed at 80$0^{circ}C$ have reactive sub-micron size which has good sinterbililty.