- COD 분석시 염소이온의 간섭작용에 관한 연구
- ㆍ 저자명
- 김종규,김남천,민달기
- ㆍ 간행물명
- 한국환경위생학회지
- ㆍ 권/호정보
- 1989년|15권 2호|pp.33-40 (8 pages)
- ㆍ 발행정보
- 한국환경보건학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Dichromate reflux method for COD analysis is one of the useful and precise way to solve the organic content of the wastewater. But the standard procedure for COD is not entirely satisfactory for sample containing appreciable amounts of inhibiting substance, especially chloride ion. Under the conditions of the established test, a big disadvantage of the method is that dichromate oxidizes chloride quantitatively to chlorine. When it is necessary to use silver sulfate as a catalyst in the COD procedure, chloride must be removed before the addition of the catalyst. Silver sulfate and mecuric sulfate forms a precipitate of AgCl and HgCl$_{2}$ separately which is not completely oxidized during the test and, therefore, cannot be corrected for. So, we evaluate and compensate the amount of chloride oxidation in the absence of chemicals during the experimental procedure. Calculation of COD is made using the following reviced formula: real COD = tested COD - 0.2277Cl.