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Preparation, Structural and Magnetic Properties of Ordered Perovskite (BaLa)(MgMo)O$_6$
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  • Preparation, Structural and Magnetic Properties of Ordered Perovskite (BaLa)(MgMo)O$_6$
저자명
조진호,홍성태,Choy. Jin-Ho,Hong. Seung-Tae
간행물명
Bulletin of the Korean Chemical Society
권/호정보
1989년|10권 1호|pp.8-12 (5 pages)
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대한화학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The polycrystalline powder of (BaLa)(MgMo)$O_6$ has been prepared at $1350^{circ}C$ in a nitrogen flowing atmosphere. The powder X-ray diffraction pattern indicates that (BaLa)(MgMo)$O_6$ has a cubic perovskite structure ($a_0$ = 8.019(3) $AA)$ with 1:1 ordering or $Mg^{2+}$ and $Mo^{5+}$ in the oxide lattice. The infrared spectrum shows two strong absorption bands with their maxima at 600(${ u}3$) and 365(${ u}4$) cm-1, which are attributed to $2T_{1U}$, modes of molybdenum octahedra MoO6 in the crystal lattice. According to the magnetic susceptibility measurement, the compound shows a paramagnetic behavior which follows the Curie-Weiss law below room temperature with the effective magnetic moment 1.60(1){$mu}B$, which is consistent with that of spin only value ($1.73{mu}B$) for $Mo^{5+}$ ($4d^1$ electronic configuration). From the thermogravimetric and X-ray diffraction analyses, it has been found that (BaLa)(MgMo)$O_6$ decomposes gradually into $BaMoO_4$, $MoO_3$ and unidentified phases above $900^{circ}C$ in an ambient atmosphere, absorbing about 0.25 mole $O_2$ per mole of Mo ion, which also supports that oxidation state of $Mo^{5+}$ in the (BaLa)(MgMo)$O_6$.