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Crystallographic Evidence for the Reduction of CO in Partially Dehydrated Silver Zeolite A
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  • Crystallographic Evidence for the Reduction of CO in Partially Dehydrated Silver Zeolite A
  • Crystallographic Evidence for the Reduction of CO in Partially Dehydrated Silver Zeolite A
저자명
Kim. Yang,Song. Seong-Hwan,Seff. Karl
간행물명
Bulletin of the Korean Chemical Society
권/호정보
1989년|10권 3호|pp.230-234 (5 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The crystal structure of $Ag^+$-exchanged zeolite A vacuum-dehydrated at $370^{circ}C$ and then treated with carbon monoxide at $$23^{circ}C$ has been determined by single crystal x-ray diffraction methods in the cubic space group Pm3m at $23^(1){circ}C$ ; a = 12.116 (2)${AA}$. The structure was refined to the final error indices $R_1;=;0.061;and;R_2$(weighted) = 0.068 using 349 independent reflections for which I > 3${sigma}(I).;3.6;Ag_+-CO$ complexes, where -CO may represent -CHO or -$CH_2OH$, were found in each large cavity. By coordination to silver atoms followed by reaction with $Ag^{circ}and;H^+$ within the zeolite, carbon monoxide has been partially reduced. In about 28% of the sodalite units, a $Ag_6(Ag^+)_2$ cluster may be present. In about 37% of the sodalite units, three $Ag^+$ ions are found on threefold axes where they may be bridged by three water molecules. The remaining 35% of the sodalite units are empty of silver species. Two $Ag^+$ ions per unit cell are associated with 8-ring oxygens. The remaining ca $$3Ag^+$ ions per unit cell have been reduced during the synthesis and have migrated to form small silver crystallities on the surface of the zeolite single crystal.