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Two Crystal structures of Fully Dehydrated Partially Magnesium Exchanged Zeolite A, $Mg_{1.5}Na_9-A;and;Mg{2.5}Na_7$-A
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  • Two Crystal structures of Fully Dehydrated Partially Magnesium Exchanged Zeolite A, $Mg_{1.5}Na_9-A;and;Mg{2.5}Na_7$-A
  • Two Crystal structures of Fully Dehydrated Partially Magnesium Exchanged Zeolite A, $Mg_{1.5}Na_9-A;and;Mg{2.5}Na_7$-A
저자명
Kim. Yang,Lee. Suk-Hee,Park. Jong-Yul,Kim. Un-Sik
간행물명
Bulletin of the Korean Chemical Society
권/호정보
1989년|10권 4호|pp.349-352 (4 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

Two Crystal structures of fully dehydrated partially magnesium exchanged zeolite A, stoichiometries of $Mg_{2.5}Na_7-A$ (a = 12.251 (1) ${AA}$) and $Mg_{1.5}Na_9-A; (a;=;12.214(1);{AA})$ per unit cell, have been determined from the 3-dimensional X-ray diffraction data gathered by counter methods. All structures were solved and refined in the cubic space group Pm3m at 21(1)$^{circ}C$. The structures of the dehydrated $Mg_{2.5}Na_7-A$ and $Mg_{1.5}Na_9-A$ were refined to yield the final error indices $R_1$ = 0.042 and $R_2$ = 0.049 with 318 reflections, and $R_1$ = 0.034 and $R_2$ = 0.032 with 252 reflections, respectively, for which I > $3{sigma}(I)$. Both structures indicate that $Mg^{2+}$ ions are coordinated by three framework oxygens and the angle substended at $Mg^{2+}$ ions, O(3)-Mg(1)-O(3) is ca. $120^{circ}$, close to the idealized trigonal planar value. $Mg^{2+}$ ions preferentially occupy 6-ring sites and $Na^+$ ions occupy 8-ring sites when total number of cations per unit cell is more than 8.