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국산(國産) 크라프트 펄프의 카르복시메틸화시(化時) 암모니아 팽윤처리(膨潤處理)가 카르복시메틸셀룰로오스와 카르복시메틸셀룰로오스 용액(溶液)의 특성(特性)에 미치는 효과(效果)
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  • 국산(國産) 크라프트 펄프의 카르복시메틸화시(化時) 암모니아 팽윤처리(膨潤處理)가 카르복시메틸셀룰로오스와 카르복시메틸셀룰로오스 용액(溶液)의 특성(特性)에 미치는 효과(效果)
저자명
안병국,안원영,Ahn. Byoung-Kuk,Ahn. Won-Yung
간행물명
목재공학
권/호정보
1990년|18권 2호|pp.25-35 (11 pages)
발행정보
한국목재공학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

To investigate the effects of swelling treatment by ammonia on characteristics of carboxymethy1cellulose(CMC) and CMC solution, the domestic kraft pulp pretreated with 5%, 10%, 15% and 20% $NH_4OH$ solution, was carboxymethylated by the standard method, and then the CMC prepared was tested. The physical properties of CMC and CMC solution, such as degree of substitution, transparency. viscosity, weight increase and solubility, were measured, and the comparison with commercial domestic CMC used as a food additive was done. The results obtained were as follows; 1. In CMC manufactured by standard solvent method, hardwood bleached kraft pulp(LBKP) was more substituted than safwood bleached kraft pulp(NBKP), and viscosity of NBKP was higher than that of LBKP. 2. When ammonia swelling treatment was done, degree of substitution gradually decreased with increasing concentration of $NH_4OH$, and degree of substitution of LBKP decreased with a larger range than that of NBKP. 3. When ammonia swelling treatment was done. transparency of CMC solution from LBKP was hardly effected, but in case of NBKP gradually increased with increasing concentration of $NH_4OH$. 4. When ammonia swelling treatment was done, viscosity of CMC solution was higher than that of CMC solution without ammonia swelling treatment. Especially, CMC of high viscosity could be manufactured in 5%, 10% concentration levels of $NH_4OH$. 5. In CMC manufactured from domestic NBKP, CMC at the range of 0.40 to 0.50 in DS was dispersed easily and quickly dissolved, and CMC at more than 0.50 in DS was dispersed slowly in water solution. 6. In comparison with commercial domestic CMC used as a food additive, CMC manufactured from domestic NBKP was higher in DS, and was lower in viscosity and transparency.