본 고에서는 Equivalent time과 Equivalent temperature를 활용하여 Kinetic parameters를 결정하는 새로운 방법을 제안하였다. 본 방법의 타당성을 두 가지의 kinetic data 즉, 계산치와 실험치를 이용하여 예시하였다. 계산치는 그 Kinetics가 잘 알려진 세 가지 화학반응에 대해 임의의 등온가열조건을 적용하여 계산하였고 실험치는 2% 설탕용액을 사용하여 0.0005N 염산용액을 사용하여 가수분해가 일어나는 정도를 효소반응을 이용하여 측정하였다. 본 방법에 의해 결정된 활성화 에너지와 Frequency factor는 각각 $104.74{pm}1.87KJ/mol$과 $5.26{ imes}10^{14)hr^{-1}$이었으며 이들 값은 보고된 결과와 잘 일치되었다.
A method for application of the equivalent time and temperature point for estimating kinetic parameters was proposed. The feasibility of the method was demonstrated with both theoretical and empirical kinetic data. The theoretical kinetic data were obtained from the arbitrarily chosen time-temperature data for three chemical reactions whose kinetics are well established. The experimental kinetic data were obtained for the acid (0.0005 N HCl) catalyzed hydrolysis of sucrose(2%). The activation energy and the frequency factor determined by the proposed method were $104.74{pm}1.87kJ/mol;and;5.62{ imes}10^{14};hr^{-1}$ respectively and the results agreed well with those obtained by a different method of kinetic parameter estimation, i.e. the linearly increasing temperature method.
