The purpose of this study is to get experimental data on the distribution of CWM (Coal- Water Mixture) droplets size and the presence of pulverized coal particles inside CWM droplets. Atomization of CWM is done by Twin-Fluid Atomizer. The operational parameters are atomizing air pressure, coal particle loading, mean size of pulverized coal particles and sampling positions across spray. Th data analysis is initiated by Impression Sampling Method(Magnesium Oxide Technique) and Photo-technique and counting works are followed. Experimental work induces following research results. The variation of particle loadings in slurry makes no appreciable effects on the mean size of CWM droplets. It is evident that atomizing air pressure has very strong effect on the atomization of slurry. The mean size of atomized fuel droplets is dramatically reduced with the increasing air pressure. The population ratio of droplets without coal particles to total number of droplets is decreased as atomizing air pressure or loading rises and the same trend is obtained as the mean size of coal particles becomes smaller but a certain tendency of coal particle presence inside droplets could not be found from the change of sampling positions.