Double coaxial are jets(annular and coaxial air jets) between which propane gas is fed was selected to study the structure of diffusion flames in turbulent shear flow. Schlieren and direct photographs are taken to visualize the flame structure. Mean and fluctuating temperatures and ion currents were measured to investigate the macroscopic and the instantaneous flame structure. The objective of this study is to understand the interaction between combustion and mixing process especially in the transition region of turbulent shear flow. The investigation reported in this paper focuses on the macroscopic and the instantaneous structures of three flames obtained. The increased mixing effect resulting from increase of Reynolds number of central air jet makes the flame bluish and short. When the velocity of surrounding air stream is higher than that of central air jet, the instantaneous flame structure is composed of coherent structure. It is considered that the flame structure of transitional region of mixing layer depends on the structure of mixing layer of non-reacting conditions.