To investigate the damage on the black pine(Pinus thunbergii) by the air pollution around Ulsan Industrial Complex, forty-six plots were set up and the effects of air pollution were evaluated with the injured index of black pine. The injured index of black pine showing the degree of air pollution from 1987 to 1988 indicated that the central area of Yeochun-dong and Youngjam-dong were heavily damaged. The effective indicaters of black pine damage from air pollution in the order of importance were the color change of one-year-old branch, the ratio of fallen needle of two-year-old branch, the degree of reducing needle, and the degree of growing shoot growth. There was a reliable relationship between the content of $SO_3$ and F in the air and the injured index of black pine. There was no significant correlation between the injured index of the black pine and the content of chemical properties in soil.