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Electrochemical Polymerization of Pyrrole from Aqueous Solutions : 2. Growth Kinetics of Polypyrrole p-toluenesulfonate Film
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  • Electrochemical Polymerization of Pyrrole from Aqueous Solutions : 2. Growth Kinetics of Polypyrrole p-toluenesulfonate Film
  • Electrochemical Polymerization of Pyrrole from Aqueous Solutions : 2. Growth Kinetics of Polypyrrole p-toluenesulfonate Film
저자명
Song. Eui Hwan,Paik. Woon-Kie,Chon. Jung-Kyoon
간행물명
Bulletin of the Korean Chemical Society
권/호정보
1990년|11권 1호|pp.41-44 (4 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The rates of electropolymerization of pyrrole from aqueous solutions containing p-toluenesulfonic acid were studied as functions of the concentration of the surfactant anions and of temperature for the polymerization on the electrode surface immersed in the solution and also for the polymerization along the solution surface. In the case of the solution-surface polymerization, the polymerization rate showed maximum as the concentration of the p-toluenesulfonic acid changed at a fixed temsperature or as the temperature was varied at a fixed concentration. The decrease of the polymerization rate with increasing concentration or with rising temperature beyond the values at the maxima is interpreted as resulting from micelle formation.