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Potential Profiles and Capacitances of an Ideally Polarizable Electrode/Hard Sphere Electrolyte System
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  • Potential Profiles and Capacitances of an Ideally Polarizable Electrode/Hard Sphere Electrolyte System
  • Potential Profiles and Capacitances of an Ideally Polarizable Electrode/Hard Sphere Electrolyte System
저자명
Kim. Sang-Youl,Vedam. K.
간행물명
Bulletin of the Korean Chemical Society
권/호정보
1990년|11권 6호|pp.487-493 (7 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

A complete potential profile of an electrical double layer is calculated from a distribution function of charged particles based upon a model where the effect of a charged electrode and the finite size of ion are explicitly included. Electrons which are distributed on the electrode surface are assumed not to penetrate the electrode/electrolyte boundary. Formation of the constant density regions and their effects on potential and the electrical double layer capacitances are studied in great detail. The distribution of surface electrons as well as the constant density regions are found to be essential in characterizing the electrical double layer. The introduction of the ion size into the prior electrical double layer model of an ideally polarizable electrode/point charged electrolyte system, shows a great improvement in its characteristics mostly at negative potential region.