This paper present a rule-based speech synthesis method for improving the naturalness of synthetic speech and using the small data base based on demisyllable units. A 12-pole Linear Prediction Coding method is used to analyses demisyllable speech signals. A syllable and vowel concatenation rule is developed to improve the naturalness and intelligibility of the synthetic speech. in addiion, phonological structure transform rule using neural net and prosody rules are applied to the synthetic speech.