Centrifugally Cast Stainless Steel generally shows similar structure to the weld in austenitic stainless steel in the point of casting. When examining this material ultrasonically, the beam does not generally propagate straightforward but rather deviates from its original direction and this phenomenon called skewing is originally caused by anisotropic material. In order to calculate the beam skewing effect theoretically, work has been performed based on a model approach which has regarded material itself as having been composed of multi-layered columnar dendrite structure and the result was compared with the one from experiment. The result from both theory and experiment showed good correlation and ultrasonic beam showed the least skewing with around 45 degree incident angle.