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목질폐재(木質廢材)의 열(熱)-화학적(化學的) 탈(脫)산소-수소첨가반응(환원반응)에 의한 액화(液化)탄화수소의 합성 (II)
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  • 목질폐재(木質廢材)의 열(熱)-화학적(化學的) 탈(脫)산소-수소첨가반응(환원반응)에 의한 액화(液化)탄화수소의 합성 (II)
저자명
이병근,Lee. Byung-Guen
간행물명
목재공학
권/호정보
1991년|19권 4호|pp.80-84 (5 pages)
발행정보
한국목재공학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Lignocellulosic biomass including acetosolv ricestraw and spruce lignin were liquefied and converted into liquid hydrocarbons by catalytic hydroliquefaction reaction. These experimental works were carried out in 1-liter-capacity autoclave using 50% tetralin and m-cresol solution respectively as soluble solvent and Ni. Pd. Fe and red mud as catalyst. $H_2$ gas was supplied into the reactor for escaltion of deoxhydroenolysis reaction. Catalyst concentrations were 1 % of raw material based on weight. The ratio between raw materials and soluble solvent are 1g and 10cc. The reaction conditions are 400-$700^{circ}C$ of reaction temperature, 10-50 atms of reaction pressure. The highest yield of hydrocarbon, so called "product oil" showed 32% and 5.5% of lowest char formation when red mud was used as catalyst. The product oil yields from those of other catalysts were in the range of 20-29%. The influence of different initial hydrogen pressures was examined in the range d 30-50 atms. A minimum pressure of 35 atms was necessary to obtain a complete recovery of souble solvent for recycling.