Evaporation rate constant, obtained by in this experimental study, of freely falling liquid fuel droplet on the condition of hot and pressurized environment are converted to critical evaporation constant according to Eq. of Ranz and Marshall. Critical evaporation constant, on constant environment pressuire, actively increase almost linearly with environment temperature increasing, but, on constant temperature, increases more or less with pressure increasing. Multycomponent droplet mixed with the fine fuel having a different of boiling point evaporate in order to boiling point, and each evaporation rate constant of mixed fuel equal to each fuel.