ZnO fine powder was prepared by the batch precipitation process using $ZnCl_2$ and hexamethylenetetramine solution as a mother solution. When the concentrations of $ZnCl_2$solution were $0.1mol/ell$ and 0.05mol/-, the particles of rod shape were obtained when the conentration of $ZnCl_2$solution was $0.01mol/ell$, the particle of plate shape was obtained. When the hexamethylenetetramine as a precipitants was used, pH was raised slow during a few minute be-cause of slow hydrolysis rate of hexamethylenetetramine. For rapid raising of pH during initial reac-tion time, $NH_4$OH was added as nucleant. When $NH_4$OH as a nucleant was added, obtained particle was shape of granular and the mean particle size was $0.41mu extrm{m}$. After calcination at $500^{circ}C$ during 1hour, all of remained organic phase was removed but the shape of particles was not changed. But pa-rticles were slightly shrunk in comparision with before calcined particles.