- Congo Red로 염색한 면섬유의 염색성에 미치는 전해질의 영향
- ㆍ 저자명
- Lee. Young-Hee,Park. Joon-Myung,Sung. Woo-Kyung,Kim. Kyung-Hwan
- ㆍ 간행물명
- 韓國染色加工學會誌
- ㆍ 권/호정보
- 1991년|3권 2호|pp.34-42 (9 pages)
- ㆍ 발행정보
- 한국염색가공학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The effects of electrolyte on dyeing properties of cotton fiber with Congo Red have been studied at 90, 70 and $40^{circ}C$. Each dyeing carried into an infinite bath with $1 imes10^{-4}$ mol/l of Congo Red and with various concentration of electrolytes. The results obtained from this study were as follow; 1. The equilibrium adsorption of dye $(C_infty)$ values decreased with increasing dyeing temperature, $C_infty$ values increased in the order KCl>NaCl>LiCl. 2. The values of apparent diffusion coefficients $(D_a)$ increased with increasing dyeing temperature, but $D_a$ values decreased in the order KCl<NaCl<LiCl. 3, $D_a$ values decreased with increasing electrolyte concentration. 4. Effect of electrolytes decreased with increasing dyeing temperature. 5. The values of standard affinities of dyeing $(- rianglemu^{circ})$, the standard heats of dyeing $(- riangleH^{circ})$, and the standard entropies $(- riangleS^{circ})$, increased in the order KCl>NaCl>LiCl. 6. Equilibrium adsorption isotherm curve were Freundlich type, and in the Equation y=a.x$^{n}$ , the values of a and n increased in the order KCl>NaCl>LiCl. 7. The value of $- rianglemu^{circ}$, $- riangleH^{circ}$, and $- riangleS^{circ}$, decreased with increasing electrolyte concentration.