In a large power transformer, insulating oil is forced to circulate for cooling the heat generated by the losses within windings and core. When insulating oil flows and rubs against various materials, such as insulating paper or core, the electrostatic charges are separated at the interface of the oil and the solid material. This paper considers the streaming electrification of various materials used in the transformer. In this study, we show that a solid material such as paper is negatively charged. On the other hand, a solid material such as core is positively charged.