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A Study on Spin-Lattice Relaxation of Methyl Protons in 2,6-Dichlorotoluene and N-Methyl Phthalimide
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  • A Study on Spin-Lattice Relaxation of Methyl Protons in 2,6-Dichlorotoluene and N-Methyl Phthalimide
  • A Study on Spin-Lattice Relaxation of Methyl Protons in 2,6-Dichlorotoluene and N-Methyl Phthalimide
저자명
Lee. Jo-Woong,Lim. Man-Ho,Rho. Jung-Rae
간행물명
Bulletin of the Korean Chemical Society
권/호정보
1991년|12권 1호|pp.47-51 (5 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Spin-lattice relaxation of methyl protons in 2,6-dichlorotoluene and N-methyl phthalimide, each dissolved in CDCl$_3$, has been studied at 34$^{circ}$C and the contribution from spin-rotation interaction to the relaxation process has been separated from that due to dipole-dipole interactions among methyl protons. The results show that the spin-rotational contributions to the initial rate of relaxation in 2,6-dichlorotoluene and N-methyl phthalimide amount to 18 and 31%, respectively, of the total relaxation rate at 34$^{circ}$C. The method of separating the spin-rotational contribution from that of dipolar interactions adopted in this paper is based on the well known fact that in an A$_3$ spin system such as methyl protons in liquid phase dipolar relaxation mechanism gives non-exponential decay of the z-component of total magnetization of protons while the random field fluctuation such as spin-rotational mechanism causes exponential decay.