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Salt Effects on the Critical Micelle Concentration and Counterion Binding of Cetylpyridinium Bromide Micelles
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  • Salt Effects on the Critical Micelle Concentration and Counterion Binding of Cetylpyridinium Bromide Micelles
  • Salt Effects on the Critical Micelle Concentration and Counterion Binding of Cetylpyridinium Bromide Micelles
저자명
Chung. Jong Jae,Lee. Sang Wook,Choi. Joon Ho
간행물명
Bulletin of the Korean Chemical Society
권/호정보
1991년|12권 4호|pp.411-413 (3 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The effects of electrolyte on the critical micelle concentration (cmc) and bromide counterion binding in the micelles of cetylpyridinium bromide (CPB) have been investigated by UV spectroscopy and conductance measurements. Salts used in this study decreased cmc in the order $Cl^-;<;Br^-;<;NO3^-$ (which parallels the lyotropic series for the inorganic anions) and the effects on cmc followed the equation proposed by Shinoda: log cmc = A - B log (cmc + [NaX]). In the equation, constant B represents the counterion binding to the micelles at cmc and for the micelle of CPB at $25^{circ}C$, B=80.76%. The association constant for the binding of counterions to long chain cations within micelles was also derived from the cmc values and counterion binding constant to the micelles.