Various types of ultrasonic techniques have been used for the estimation of compressive strength of concrete structures. However, conventional ultrasonic velocity method using only longitudial wave cannot be determined the compressive strength of concrete structures with accuracy. In this paper, by using the introduction of multiple parameter, e. g. velocity of shear wave, velocity of longitudinal wave, attenuation coefficient of shear wave, attenuation coefficient of longitudinal wave, combination condition, age and preservation method, multiple regression analysis method was applied to the determination of compressive strength of concrete structures. The experimental results show that velocity of shear wave can be estimated compressive strength of concrete with more accuracy compared with the velocity of longitudinal wave, accuracy of estimated error range of compressive strength of concrete structures can be enhanced within the range of ${pm}$10% approximately.