The purpose of this study is to identify the radiative heat transfer augmentation by a coaxial cylinder introduced in the infinite cylindrical pipe enclosing a participating gas. The gas is either a mixture of water vapor and carbon dioxide or gray. The gas is assumed to be homogeneous at a constant temperature, and has a refractive index of unity. All of the surfaces are opaque and gray, diffusely emitting and reflecting at a constant temperature, The effect of system diameter, diameter ratio, wall emittances, gas and surface temperatures, mixture component on heat transfer augmentation are studied by using the zone method with participating gas radiative properties evaluated from the weighted sum of gray gases model. From the radiative equilibrium condition, the installed wall temperature is formulated and calculated by the iteration method. If the medium is a gray gas, the augmentation observed are negligible. For the range of values studied for a real gas, if the system diameter is larger than about 0.1m the augmentation parameter increases up to about 1.2 as the system diameter increases. The augmentation parameter have a maximum value at a certain diameter ratio. The augmentation parameters decreases as the emittance of the installed wall decreases. If the gas temperature is higher than about 1273 k, the augmentation parameter decreases as the gas temperature increases.