Profiles of soot volume fraction, average diameter and particle number density have been measured using a light scattering and extinction technique in a coannular propane diffusion flame at atmosperic pressure. Temperature profiles were also obtained using a thermocouple technique. Measurements show that soot is first observed to form low in the flame in an annular region inside the main reaction zone. At higher locations this annular region widen until entire flame is observed to contain particles. Soot volume fraction and particle diameter profiles peak some 1mm on the fuel side of peak temperature and increase with height to oxidation region. Number density of the flame core drop steeply from formation region to growth region and relatively invariant to some height and decay out at flame tip.