Film boiling heat transfer characteristics in liquid-liquid systems are studied experimentally. Liquid gallium as a heating liquid, n-pentane, freon-113, and ethanol are used as boiling liquids. In gallium-n-pentane and gallium-freon-113 systems the minimum film boiling point occurred at higher temperature than those observed in copper-boiling liquid systems. However MFB point occurred almost at the same temperature for the case of ethanol. This difference are due to the effects of contact angle and interfacial agitations in gallium-boiling liquid systems. Film boiling heat transfer rate, for the gallium-boiling liquid systems considered in this work, found to be approximately 10% higher than those in copper-boiling liquid systems, whose main cause is believed to be gallium-boiling liquid interfacial agitations affected by the density ratio between gallium and boiling liquid.