Dispersion of pollutant in a mountainous area is simulated in a wind tunnel. In the northwest side of the terrain model, the sea level is assumed. Wind from the sea initially confronts hills along the shoreline, a line of large buildings next, and finally a valley between high mountains in the south and in the east. In the northwest wind conditions, severe flow separation occurs in the lee side of hills, even beyond the building area. Pollutant from the buildings is trapped in this region and its concentration is the highest. In the west wind conditions, pollutant from the buildings flows along the hills aslant the main wind direction in this case. Since large valley is located in the downstream, pollutant tends to disperse along the valley.