Simple correlation analysis, factor analysis, and multi-variate analysis have been performed to analyze the relationship between air pollution and meteorological factors for air pollution and meteorological data measured at Kwanghwamun in Seoul during the period of one year(January 1990 $sim$ December 1990). As a result of simple correlation and factor analysis, $SO_2$, TSP and CO concentrations have shown high negative correlation with temperature and among these indicating that these are related with pollutant emission trend based upon heating fuel usage. Ozone has a good corrleation with solar radiation and relative humidity to have a closed relation with $O_3$ generation reaction mechanism. The result of multi-variate correlation analysis shows that the concentration of $SO_2$ and CO are adequate for correlation model with ambient temperature and wind speed and $O_3$ concentrations are adequate for that with solar radiation and wind speed. $SO_2$ and CO levels are considered to be affected first of all by heating fuel usage as a emssion source and wind speed as a dispersion effect. The $SO_2$ concentration in the condition that the temperature fall below zero is explained by multilicative model with wind speed, only one variable.