In this thesis, the electrification phenomenon was studied by measurement of charging current and discharging current in polymers when the carriers generated by corona discharge were supplied to the surface of polymers. Corona charging current of PVC, polar and noncrystalline polymer, was larger than that of nonpolar and amorphous polymers. Corona charging current on the specimen of naked upper surface (CIM) was larger than charging current on the specimen of electrode made. Carrier injection differed from interfacial phase of polymer surFace. The transfer phenomenon vaned with chemical structure of polymer and then the polar effect of PVC was remarkable because of large electron affinity of Cl. In the characteristics of discharging current of PVC, the abnormal current was observed. It was supposed that this phenomena presented the trap of injected carriers in PVC and that static electricity phenomenon was generated by trap.