Energy system models have been broadly used for the solution of the assessment of technical and economical characteristics in the national energy systems. The purpose of this study is to overview the structures, potentials and usefulness of system models for energy technology assessment. The conventional models developed so far are not aquate to analyze the energy and environmental problems simultaneously. Energy system models integrated by multiobjective programming are also reviewed and discussed in this paper to judge their usefulness and applicability in simultaneously analyzing the energy and environmental problems.