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Chemistry of Rethenium Hydridonitrosyl Complexes Containing Chelating Triphosphines II-Structures of $[RuH_2(NO)P_3]^+$ ($P_3$ : Chelating Triphosphines)
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  • Chemistry of Rethenium Hydridonitrosyl Complexes Containing Chelating Triphosphines II-Structures of $[RuH_2(NO)P_3]^+$ ($P_3$ : Chelating Triphosphines)
저자명
Lee. Ik Mo,Meek. Devon W.,Gallucci. Judith
간행물명
Bulletin of the Korean Chemical Society
권/호정보
1992년|13권 5호|pp.498-503 (6 pages)
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대한화학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The protonation of RuH(NO)(Cyttp) resulted in the formation of $[RuH_2(NO)(Cyttp)]^+$ which is characterized as a classical cis-dihydried complex. This complex is fluxional and the intramolecular process involving a molecular hydrogen complex is proposed. This mechanism was further supported by the reactivity of this complex toward neutral 2-electron ligands. On the other hand, it failed to detect the existence of $[RuH_2(NO)(etp)]^+$ probably due to instability of the complex but the crystal structure of $[Ru(PMe_3)(NO)(etp)]^+$ formed by the protonation of RuH(NO)(etp) followed by the addition of $PMe_3$ was determined to have a trigonal bipyramidal structure with a linear NO in the equatorial plane and a facial etp ligand. The crystals are monoclinic, space group P21/n, with unit cell dimensions a = 14.130(2), b = 21.026 (3), c = 14.760 (1) ${AA}$, ${eta}$ = 97.88 $(l)^{circ}$ V = 4344 ${AA}^3$, Z = 4, R = 0.046 and $R_w$ = 0.056 for the 4779 intensities with $F_o^2 > 3{sigma}(F_0^2)$ and the 440 variables.