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Fourier Transform Infrared Matrix Isolation Study of Acetonitrile in Solid Argon
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  • Fourier Transform Infrared Matrix Isolation Study of Acetonitrile in Solid Argon
  • Fourier Transform Infrared Matrix Isolation Study of Acetonitrile in Solid Argon
저자명
Kim. Hack Sung,Kim. Kwan
간행물명
Bulletin of the Korean Chemical Society
권/호정보
1992년|13권 5호|pp.520-526 (7 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The intramolecular fundamental vibrations of $CH_3CN$ trapped in solid argon matrix have been reinvestigated by means of FT-IR spectroscopy in the spectral range of 4000-500 $cm^{-1}$. By employing a quantum detector, infrared spectra could be obtained at matrix to solute ratio of 10000, allowing the clarification of the peaks due to monomeric species more clearly. Temperature controlled diffusion was initiated to identify the dimeric and polymeric species in terms of difference spectra. The assignments of monomeric and dimeric species are found, in general, to agree with the earlier work performed at higher concentration (Ar/$CH_3CN$ = 1500) using a dispersive spectrometer. Nonetheless the difficulty of minute differences between the earlier infrared and Raman spectroscopic results could be resolved. Moreover, the previously unnotified peaks due to polymeric species have been identified.