Electrostatic Precipitator has been widely used to get high efficiency which is required for collection of fine particles. In order to provide collection efficiency and size distribution data for a pilot electrostatic precipitator, a pilot study has been conducted on fly ash from pulverized coal burning apparatus. The aims of this study are to investigate characteristics of electric charge, to measure collection efficiency varied with the applied voltage, to get an optimum current and current density. Optimum current density was obtained to 0.7mA/$cm^2$ at the average electric field strength 2.33kV/cm in this experiment. Maximum particle collection efficiency was indicated 99.21% at the applied voltage 7kV. Finally, particle size distribution is also compared with photographic results. Both coarse and fine particles at the range of 0.5$sim$2$mu$m and 3$sim$10 SEM $mu$m were clearly removed by increasing applied voltage.