Boron cabride was prepared from the mixture of metal boron and graphite powders in Argon atmosphere by Self-propagating High-temperature Synthesis Chemical furnace. The most excellent mechanical properties were in the case that Fe was added as a sintering agent before the synthesis of the B4C in the Chemical furnace. Sintered B4C-5wt% Fe specimen showed the relative density of 95%, of theoretical value, and 3-point-flexural strength of 380MPa.