- 다결정 $Fe_{1+X}Eu_{1-X}O_{3}$의 결정구조 연구
- ㆍ 저자명
- 김정기,서정철,한은주
- ㆍ 간행물명
- 韓國磁氣學會誌
- ㆍ 권/호정보
- 1993년|3권 2호|pp.101-107 (7 pages)
- ㆍ 발행정보
- 한국자기학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
다결정 $Fe_{1+X}Eu_{1-X}O_{3}$(x=-0.06, 0.0, 0.1, 0.2, 0.3과 0.4)의 결정구조를 X-선 회절과 $M"{o}ssbauer$ 분광학 방법에 의해서 연구하였다. X-선 회절선과 $M"{o}ssbauer$ 분광 스펙트럼 분석 결과 $-0.06{leq}x{leq}0.0;과;0.2{leq}x{leq}0.3$ 영역의 시료에서는 각각 orthoferrite와 garnet 단일 결정상을 나타낸다. 그러나, $0.0
The crystallographic properties of the polycrystalline materials $Fe_{1+X}Eu_{1-X}O_{3}$(X = -0.06, 0.0, 0.1, 0.2, 0.3, 0.4) have been studied by the methods of X-ray diffraction and $M"{o}ssbauer$ spectroscopy. The results showed that the samples with the composition range of $0.2{leq}x{leq}0.3$ had the garnet crystal phase, while those with $-0.06{leq}x{leq}0.0$ had the orthoferrite phase. However, with the tendency for the orthoferrite phase to convert into the trigonal phase via garnet phase as increasing the composition x, the orthoferrite-garnet and garnet-trigonal phase coexisted dominantly in the range of 0.0 < x < 0.2 and $0.4{geq}x$, respectively. The analyzed results of $M"{o}ssbauer$ spectrum indicated existence of some vacancies in the d-site of garnet phase, which can be related to the change of intensity in X-ray diffraction patterns.