The shielding effectiveness of materials is determined by measuring the ratio of the incident electromagnetic power to that which passes through the material under test. The measurement system is constructed using several test fixtures, tracking generator, spectrum analyzer, step attenuator, RF switches, and amplifiers, etc.. The automation of measurements is completed using a personal computer. Especially, incident power, reflected power, and transmitted power are measured with only one spectrum analyzer using a dual directional coupler and RF switches. Therefore the system is to be used in design of shielding materials, as well as shielding effectiveness measurements. This system has dynamic range of more than 120 dB in the frequency range of 10 MHz to 1 GHz, and it can be used to measure shielding effectiveness of composite materials.