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Humic acid 제거를 위한 국산 입상활성탄의 흡착성능 평가에 관한 연구
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  • Humic acid 제거를 위한 국산 입상활성탄의 흡착성능 평가에 관한 연구
저자명
신성교,김종구,박청길,Shin. Sung-Gyo,Kim. Jong-Gu,Park. Cheong-Gil
간행물명
한국환경과학회지
권/호정보
1993년|2권 1호|pp.73-81 (9 pages)
발행정보
한국환경과학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Adsorption process using granular activated carbon(GAC) has been considered as one of the most effective water treatment technologies to remove humic acid which is recon- niEed as trihalomethane(THM) precursor in chlorination. To design the most effective GAC process, it is necessary to conduct the test of adsor- ption performance by means of isothem, batch rate and column studies and to select the most effective activated carbon according to raw materials of GAC - lignite and coconut shell. The objective of this study is to investigate the adsorption performance of humid acid on two activated carbons - lignite activated carbon(LAC) and coconut shell activated car- bon(CAC) made in Korea. It is available to represent UV-abs and trihalomethane formation potential(THMFP) as concentration of humic acid due to good relationship. The adsorption capacity of humid acid is not concerned with surface area of activated carbon but with pore size related to about $100{AA}$, and then LAC forming at the extent of mesopore is found to be eight times more effective in adsorption capacity than CAC forming at micropore. The adsorption capacity of LAC and CAC is better at pH 5.5 than at pH 7. Pore and surface diffusion coefficients calculated from the diffusion model are $7.61 imes10^{-13}m^2/sec$, $3.52 imes10^{-15}m^2/sec$ for CAC, and $3.38 imes10^{-12}m^2$/sec and $Ds=1.48{ imes}10^{-15}m^2/sec$ for GAC respectively. From the results of column test it shows that the performance of LAC is also better than CAC and the optimal EBCT(Empty Bed Contact Time) is 4.52min. and activated carbon removes selectively the components of humic acid to be easily formed to THM.