- 포피린-메탈 복합체를 이용한 TNT 폐수의 처리
- Abatement Study of TNT Wastes by Porphyrin-Metal Complexes
- ㆍ 저자명
- 조정국,우인성
- ㆍ 간행물명
- 한국산업안전학회지
- ㆍ 권/호정보
- 1993년|8권 4호|pp.127-132 (6 pages)
- ㆍ 발행정보
- 한국안전학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Porphyrin-catalyzed reduction of TNT to triaminotoluene was performed in both batch reactions and a continuous process. Packed-bed reactors were used to study porphyrin-catalyzed reduction in a continuous process. A reactor was packed with DEAD(diethylaminoethyl)-substituted glass beads on which $Co^{+3}$_centered deuteroporpgyrin Ⅸ, -2, 4-disulfonic acid was immobilized, and another containing only DEAE glass beads was used as a control. The porphyrin exhibited catalytic activity in its immobilized state up to 100 hours of operation. Based on the successful abatement of nitrobodies by porphyrin-catalyzed reduction in both batch and continuous process, this process is recommended to be used as a pretreatment for biological treatment or carbon adsorption treatment of TNT wastes.