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Two Crystal Structures of Dehydrated Fully $Ca^{2+}$-Exchanged Zeolte A Reacting with Rubidium Vapor
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  • Two Crystal Structures of Dehydrated Fully $Ca^{2+}$-Exchanged Zeolte A Reacting with Rubidium Vapor
  • Two Crystal Structures of Dehydrated Fully $Ca^{2+}$-Exchanged Zeolte A Reacting with Rubidium Vapor
저자명
Song. Seong-Hwan,Kim. Yang
간행물명
Bulletin of the Korean Chemical Society
권/호정보
1993년|14권 2호|pp.258-262 (5 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Two single crystals of fully dehydrated $Rb^+$ -exchanged zeolite A have been prepared by the reduction of all $Ca^{2+}$ ions in dehydrated $Ca_6$-A by rubidium vapor. Their structures were determined by single crystal X-ray diffraction methods in the cubic space group Pm3m (a=12.160(2) $^{AA}$ and 12.166(2) $^{AA}$) at 22(1)$^{circ}$C. In these structures, 12.4(2) to 13.3(2) Rb species are found per unit cell, more than 12 Rb$^+$ ions needed to balance the anionic charge of the zeolite framework, indicating that the sorption $Rb^0$ has occurred. In each structure, three $Rb^+$ ions per unit cell are located at the centers of the 8-rings. Six to eight $Rb^+$ ions are found opposite the 6-rings on threefold axes, and three $Rb^+$ ions are found in a sodalite unit. About 0.5 $Rb^+$ ion lies opposite a 4-ring. The structural analysis indicates the presence of a triangular rubidium cluster in the sodalite cavities. The triangular rubidium clusters may be stabilized by the coordination to two and/or three rubidium ions in the large cavity. Therefore, this cluster may be viewed as $(Rb_5)^{4+}$ and/or $(Rb_6)^{4+}$.