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Complexation of Cadmium(II) with Soil Fulvic Acid
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  • Complexation of Cadmium(II) with Soil Fulvic Acid
  • Complexation of Cadmium(II) with Soil Fulvic Acid
저자명
Lee. Me Hae,Choi. Se Young,Moon. Hichung
간행물명
Bulletin of the Korean Chemical Society
권/호정보
1993년|14권 4호|pp.453-457 (5 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Cadmium(II) complexation by a well characterized soil fulvic acid (FA) from the Okchun Metamorphic Belt were studied at pH of 6.0 in 0.1 M $NaClO_4$ using the ultrafiltration technique. The conditional stability constants thus obtained were log K= 3.90${pm}$0.15 and 3.99${pm}$0.12 $L{cdot}mol^{-1}$ at fulvic acid concentrations of 101 and 226 mg${cdot}L^{-1}$ respectively. When free cadmium ion concentration was measured directly using an ion selective electrode, log K of 4.12${pm}$0.03 $L{cdot}mol^{-1}$ was obtained. These results show that fulvic acid forms predominately 1 : 1 complex with $Cd^{2+}$ ions. The maximum binding ability of this polyelectrolyte material was 0.886 mmol Cd/g FA. The average gram formula weight of fulvic acid was estimated to be 1130 daltons.