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Encapsulation Characteristics of Gas Molecules in the Cavities of Zeolite A
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  • Encapsulation Characteristics of Gas Molecules in the Cavities of Zeolite A
  • Encapsulation Characteristics of Gas Molecules in the Cavities of Zeolite A
저자명
Kwon. Jin Hyun,Cho. Kee Heon,Kim. Hae Won,Suh. Soong Hyuck,Heo. Nam Ho
간행물명
Bulletin of the Korean Chemical Society
권/호정보
1993년|14권 5호|pp.583-588 (6 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

Encapsulation capacities $(V_{gas})$ of, $H_2,;N_2,;CO,;CH_4$ and CO, for $Cs_{2.5}Na_{9.5}-A (C_s-A)$ and $Na_{12}$-A (Na-A) zeolites have been measured in order to understand the effect of molecular properties on the $V_{gas}$. With appropriate number of large blocking cations on the main windows of cavities in zeolite A, gas molecules can be encapsulated in both the ${alpha}$ -and ${eta}$-cages, resulting in much large $V_{gas}.;V_{gas}$ is proportional to the encapsulation pressure (Pe) and is also dependent on the molecular properties of encapsulated gases themselves, especially on intermolecular forces originated from the quadrupole moments of molecules in the molecular-dimensioned cavities of zeolite A. At the low range of Pe, molecules with larger $V_{gas}$ and intermolecular forces apparently have smaller increasing tendencies of $V_{gas}$ upon increases in Pe, showing a linear relationship between the tendencies and intermolecular forces rather than their sizes. Interactions between encapsulated molecules of $CH_4$ and framework of Cs-A have been estimated and they seem to depend on the number of encapsulated molecules per unit cell. On the basis of calculated density of $CO_2$, presence of liquid-like phase for the encapsulated molecules in the molecular dimensioned cavities of zeolite A is postulated.