Statistical calibration is a useful technique for achieving compatibility between two different measurement methods, and it usually consists of two steps : (1) estimation of the relationship between the standard and nonstandard measurements, and (2) prediction of future standard measurements using the estimated relationship and observed nonstandard measurements. A predictive multivariate errors-in-variables model is presented for the multivariate calibration problem in which the standard as well as the nonstandard measurements are subject to error. For the estimation of the relationship between the two measurements, the maximum likelihood (ML) estimation method is considered. It is shown that the direct and the inverse predictors for the future unknown standard measurement are the same under ML estimation. Based upon large-sample approximations, the mean square error of the predictor is derived.