- 아미드기를 가진 열방성 백정고분자의 제조 및 물성 (I)
- ㆍ 저자명
- 김한도,구영석
- ㆍ 간행물명
- 韓國纖維工學會誌
- ㆍ 권/호정보
- 1994년|31권 1호|pp.50-56 (7 pages)
- ㆍ 발행정보
- 한국섬유공학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
A series of thermotropic liquid crystalline(LC) copolymers based on p-acctoxybcnzoic acid(p-ABA)/terephthalic acid(TPA)/low inherent viscosity(IV) PET/Melton/2.7- diacetoxynaphthalene(2.7-DAU) was prepared by melt polymerization. The compositions of these monomers in the LC-copolyesters were varietal as a means of manipulating inherent viscosity and properties. Highly anisotropic melts were observed indicating the presence of nematic rnesophase. The thermotropic liquid crystalline copolymer exhibited a well tleveloped and highly oriented fibrillar structure. Copolymers with inherent viscosities of 0.6~1.9 that were processiblic in the temperature range of 200~23$0^{circ}C$ were obtained. The degradation temperature decreased with increasing amide unit content. The composition of PET/Melton affected the glass trailsition of LC-copolymers insignificantly, however, the glass transition temperatures depended on the total composition of the LC-copolymers significantly.