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전도성 Poly(carbonate)/poly(pyrrole) 복합체의 제조 및 전기적 성질
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  • 전도성 Poly(carbonate)/poly(pyrrole) 복합체의 제조 및 전기적 성질
  • Preparation and Electrical Properties of Electroconductive Poly(carbonate)/poly(pyrrole) Composite
저자명
박연흠,오효승
간행물명
韓國纖維工學會誌
권/호정보
1994년|31권 10호|pp.755-762 (8 pages)
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한국섬유공학회
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정기간행물|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Electrically conducting Poly(carbonate) (PC)/poly(pyrrole) (PPy) composite films were synthesized by exposing PC films containing ferric chloride as an oxidant to pyrrole vapour under various polymerization conditions. and their electrical conductivity and morphology were studied. After pyrrole was polymerized in PC matrix for two hours, the composite films showed the conductivity as high as 10-4~10-3S/cm and it increased with the concentration of the oxidant and the polymerization time and decreased with the polymerization temperature. Threshold conductivity was observed when the content of PPy in PC/PPy composite film was ca. 4.5~5 weight percent. The formation of PPy in PC matrix was confirmed by FT-IR spectra anal scanning electron micro-graphs. The x-ray diffraction curves indicated that talc structure or Pc/PPy composite film was amorphous. The conductivity increased one order of magnitude by mechanical stretching.