- 천연 Mordenite로부터 X-형 제올라이트 합성에 관한 연구
- ㆍ 저자명
- 이미재,조재훈,허혜경,최병현
- ㆍ 간행물명
- 요업학회지
- ㆍ 권/호정보
- 1994년|31권 12호|pp.1570-1576 (7 pages)
- ㆍ 발행정보
- 한국세라믹학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Effect of Na2O/SiO2 molar ratio, calcining temperature and addition of NaCl were investigated on the hydrothermal formation of X-type zeolite from the natural mordenite, which is a kind of rock deposited abundantly in kuryong po. Pulverized mordenite was first mixed with NaOH or NaOH-NaCl solution, and crystallized under hydrothermal condition at 90~10$0^{circ}C$ for 10 hrs. Optimum condition for synthesis of the X-type zeolite were circled1 the ratio Na2O/SiO2, NaCl/Al2O3 and H2O/Na2O:0.68, 11.4 and 40, respectively, circled2 calcining temperature of starting materials: 90$0^{circ}C$, circled3 aging time: 48 hrs. and circled4 crystallization temperature: 10$0^{circ}C$. The yield of X-type zeolite under the optimum condition was about 55~60%, and the major crystallized X-type zeolite was faujasite phase. Zeolite of then type X was crystallized when NaCl was added to treating solution with in the limit 14.25 of NaCl/Al2O3 molar ratio. As the calcination temperature (from 50$0^{circ}C$ to 95$0^{circ}C$) of starting materials increases, yield of zeolite x increase.