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A Modified Adsorption Model for Retention of Nonpolar Solutes in Reversed Phase Liquid Chromatography
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  • A Modified Adsorption Model for Retention of Nonpolar Solutes in Reversed Phase Liquid Chromatography
  • A Modified Adsorption Model for Retention of Nonpolar Solutes in Reversed Phase Liquid Chromatography
저자명
Cheong. Won Jo
간행물명
Bulletin of the Korean Chemical Society
권/호정보
1994년|15권 1호|pp.15-20 (6 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The adsorption model in reversed phase liquid chromatography has been critically examined. It has been found that use of the Everett type surface activity coefficient for the solute in the stationary phase is not useful to study the retention characteristics of a nonpolar solute. We suggest a modified model. In this model it is assumed that the displaced modifier molecules from the surface monolayer do not transfer into the bulk mobile phase but stick to the nonpolar solute which has displaced them. In addition, we prefer to use an apparent stationary phase activity coefficient of the soluie instead of the Everett type activity coefficient. This modified adsorption model well explains the mobile and stationary phase effects on the solute retention upon variation of mobile phase composition.