The objective of this paper is to evaluate the material properties of SA106 Gr. C carbon steel and its associated weld manufactured for main steam system of Yonggwang 3,4 nuclear generating stations. A total of 43 tensile and 35 fracture toughness tests were performed and the effects of various parameters such as pipe size, crack plane orientation, test temperature, welding on material properties were discussed. Test results show that the effects of crack plane orientation, test temperature, and welding on fracture toughness were significant while the effects of pipe size, specimen orientation and test temperature on tensile properties were negligible. Especially the dependence of J-R curves on the crack plane orientation appears to be the characteristics of carbon steel.