A study of radiative heat heat transfer has been done in the non-orthogonal coordinate system utilizing the finite volume method and the P.1 approximation. Radiation of absorbing, emitting and scattering media in a concentric annulus has been solved using the non-orthogonal coordinate and the calculations were compared with the existing results. The results obtained from the analysis using the finite volume method are in good agreement with the existing calculations for all optical thicknesses. It was also shown that for only optically thick cases, P-1 approximation can be used in a non-orthogonal coordinate. Convective heat transfer analysis has been carried out to obtain the temperature fields in a cross flow around a circular cylinder and the finite volume method was applied in the non-orthogonal coordinate system to analyze radiative heat transfer. Effects of the optical thickness, the ratio of the surface temperature of the cylinder tot he free stream temperature, and the scattering albedo on radiation have been presented.